544160 Effect of Manganese and Zeolite Composition on Zeolite-Supported Nickel Catalysts for Dry Reforming of Methane

Wednesday, June 5, 2019: 2:51 PM
Republic ABC (Grand Hyatt San Antonio)
Aaron Najfach and Catherine Almquist, Chemical, Paper, Biomedical Engineering, Miami University, Oxford, OH

Dry reforming of methane (DRM) is a reaction of interest for utilizing two greenhouse gases, carbon dioxide and methane, for syngas production. Catalysts are used to facilitate DRM as high temperatures are required. Noble metals are chosen for their effectiveness; however, these metals are expensive. Nickel as a substitute for DRM catalysts has interest for its low relative cost while still exhibiting effectiveness. Carbon deposition from side reactions is a concern as it causes catalysts fouling. To address this, addition of a second metal has shown success at facilitating the consumption of built-up carbon. Manganese has shown promise as an inexpensive second metal for this purpose. This study examines the effect of manganese loading on nickel catalysts and the effect different zeolites have on DRM. Samples were characterized with BET analysis, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Thermogravimetric Analysis (TGA). Catalysts were tested for activity and carbon deposition. It was found that the addition of manganese has a beneficial effect on reducing catalyst fouling. It was also found, over 24 hours, zeolite type had some effect on catalyst activity and may influence carbon formation. The role of manganese and sodium on zeolite destruction is also discussed.

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