470672 Origins of Concentration Gradients for Diffusiophoresis

Tuesday, November 15, 2016: 2:00 PM
Market Street (Parc 55 San Francisco)
Darrell Velegol1, Rajarshi Guha2, Manish Kumar2 and Astha Garg3, (1)Chemical Engineering, Penn State University, University Park, PA, (2)Department of Chemical Engineering, Pennsylvania State University, University Park, PA, (3)Penn State University, University Park, PA

Fluid and particle transport that is driven by gradients of pressure, gravity, or electro-magnetic potential is well-known and studied in many fields. A subtler type of transport, called diffusiophoresis, occurs in a gradient of chemical concentration, either electrolyte or non-electrolyte. Although this mechanism of particle transport is well-known, the diffusiophoresis mechanism is often considered to be an esoteric laboratory phenomenon. However, in this talk it is shown that concentration gradients can develop in a surprisingly wide variety of physical phenomena – imposed gradients, asymmetric reactions, dissolution, crystallization, evaporation, mixing, sedimentation, and others – so that diffusiophoresis is in fact a very common transport mechanism in complex fluids, in both natural and artificial systems. It is anticipated that in georeservoir extractions, physiological systems, drying operations, laboratory and industrial separations, crystallization operations, membrane processes, and many other situations, diffusiophoresis is already occurring – often without being recognized – and that opportunities exist for designing this transport to great advantage. In this talk methods are shown for identifying when diffusiophoresis might be important, and for analyzing transport in complex fluid systems, from both a modeling and experimental standpoint.

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See more of this Session: Hydrodynamics of Active Fluids
See more of this Group/Topical: Engineering Sciences and Fundamentals