468632 Molybdenum Silicide and Disulfide Protection Schemes for Silicon Photocathodes
Molybdenum disulfide (MoS2) is a low permeability material known for its excellent stability and HER activity in acid. We have previously demonstrated MoS2 protected silicon photocathodes which operate for 100 hrs without significant loss of activity.3 Here, we further this study to design strategies, such as the utilization of a molybdenum silicide interface layer, for improved activity and >800 hour stability with unchanged photoelectrochemical performance (onset potential, fill factor and light limited photocurrent density), which is among the best performance of any precious metal free photocathode.
Critical to developing future electrodes with enhanced stability, we probe the failure mechanism of the MoS2 protected photocathodes. By XPS we observe that the MoS2 is fully absent post stability testing. Detailed failure mechanisms of the photocathodes and electrolyte are uncovered by electrochemical methods, SEM, Raman microscopy and ICP. Furthermore, we implement increased light intensity, as well as light and dark cycling to probe accelerated durability testing protocols utilizing MoS2 protected photocathodes. From such analyses we facilitate insightful design of future corrosion resistant protection schemes.
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