467837 Persistently Auxetic Materials (PAMs): Engineering the Poisson Ratio of 2D Self-Avoiding Membranes Under Conditions of Non-Zero Anisotropic Strain
467837 Persistently Auxetic Materials (PAMs): Engineering the Poisson Ratio of 2D Self-Avoiding Membranes Under Conditions of Non-Zero Anisotropic Strain
Wednesday, November 16, 2016: 1:06 PM
Golden Gate 4 (Hilton San Francisco Union Square)
Entropic surfaces represented by fluctuating 2D membranes are predicted to have desirable mechanical properties when unstressed, including a negative Poisson’s ratio (“auxetic” behavior). Herein, we present calculations of the strain-dependent Poisson ratio of self-avoiding 2D membranes demonstrating desirable auxetic properties over a range of mechanical strain. Finite size membranes with unclamped boundary conditions have positive Poisson’s ratio due to spontaneous non-zero mean curvature, which can be suppressed with an explicit bending rigidity in agreement with prior findings. Applying longitudinal strain along a singular axis to this system suppresses this mean curvature and the entropic out-of-plane fluctuations, resulting in a new, molecular scale mechanism for realizing a negative Poisson’s ratio above a critical strain, with values significantly more negative than the previously observed zero-strain limit for infinite sheets. We find that auxetic behavior persists over surprisingly high strains of more than 20% for the smallest surfaces, with desirable finite size scaling producing surfaces with negative Poisson’s ratio over a wide range of strains. These results promise the design of surfaces and composite materials with tunable Poisson’s ratio by pre-stressing platelet inclusions or controlling the surface rigidity of a matrix of 2D materials.
See more of this Session: Advanced Structural Composites
See more of this Group/Topical: Materials Engineering and Sciences Division
See more of this Group/Topical: Materials Engineering and Sciences Division