465069 Molybdenum Disulfide As a Protection Layer and Catalyst for Gallium Indium Phosphide Solar Water Splitting Photocathodes
Our GaInP2 photocathodes demonstrated no loss in performance (photocurrent onset potential, fill factor, and light limited current density) until 60 hours of operation which represents a five-hundred fold increase in stability compared to bare p-GaInP2 samples tested in identical conditions.2 We believe this to be one of the first successful attempts to stabilize GaInP2 using a thin film protection layer scheme. Furthermore, as this protection scheme has previously been used successfully on silicon photocathodes3, this work highlights the potential for MoS2 to be used as a thin film protection layer for many different semiconductor water splitting devices that are unstable in acid. Using a custom-designed flow cell coupled with various microscopic techniques, we gained a greater understanding of the failure mechanisms of MoS2 as a thin-film protection layer. We discovered that pinhole formation in the MoS2 layer exposes the GaInP2 substrate, which readily corrodes in the acidic conditions, ultimately leading to device degradation. The flow cell further allowed us to capture the time scale of this pinhole formation. These insights represent a deeper understanding of MoS2 as a protection layer and can be leveraged to improve the stability of thin film protected semiconductor water splitting devices.
(1) Khaselev, O.; Turner, J. A., A Monolithic PhotovoltaicPhotoelectrochemical Device for Hydrogen Production Via Water Splitting. Science 1998, 280, 425427.
(2) Britto R.J., Benck J.D., Young J.L., Hahn C., Deutsch, T.G., Jaramillo T.F., Molybdenum Disulfide as a Protection Layer and Catalyst for Gallium Indium Phosphide Solar Water Splitting Photocathodes. Journal of Physical Chemistry Letters. Accepted (2016)
(3) Benck, J. D.; Lee, S. C.; Fong, K. D.; Kibsgaard, J.; Sinclair, R.; Jaramillo, T. F., Designing Active and Stable Silicon Photocathodes for Solar Hydrogen Production Using Molybdenum Sulfide Nanomaterials. Advanced Energy Materials 2014, 4, 18