464901 Microstructure and Yielding of Microfiber Gels
Wednesday, November 16, 2016: 2:00 PM
Market Street (Parc 55 San Francisco)
Extended Abstract: File Not Uploaded
Complex fluids have been studied and developed throughout most sectors of industry and medicine because of their unique rheological properties. Suspending colloidal particles with attractive interactions to form a network is a common way to impart a yield stress to a fluid. Large aspect ratio cellulose microfibers are able to a form poroelastic network at low volume fractions via aggregation and entanglement, forming a gel without significantly modifying viscosity. The gels have a small but useful yield stress and a better ability to suspend particles than non-interacting higher volume fraction glasses because the sparse fiber networks can significantly restructure at small strains. Yielding behavior can thus strongly depend on the fluid microstructure.
In our study, a new active microrheology technique is developed and applied to study deformation and yielding of aqueous cellulose fiber gels. Confocal imaging shows how gel yield stress relates to structural deformation rate because of localized network restructuring. Such response is advantageous to applications like surface coatings, nasal sprays, cosmetics, and foods. Understanding the mechanism of rate- and length-scale dependent yielding, and relating microstructure changes to bulk rheology, will enhance our ability to formulate, model, and design complex fluids with novel performance.