464901 Microstructure and Yielding of Microfiber Gels

Wednesday, November 16, 2016: 2:00 PM
Market Street (Parc 55 San Francisco)
Patrick T. Spicer, Chemical Engineering, University of New South Wales, Sydney, Australia, Jie Song, Chemical Engineering, UNSW Australia, Sydney, Australia, Todd M. Squires, UCSB Chemical Engineering, University of California, Santa Barbara, Santa Barbara, CA and Marco Caggioni, Microstructured Fluids Group, Procter and Gamble Co., West Chester, OH

Complex fluids have been studied and developed throughout most sectors of industry and medicine because of their unique rheological properties. Suspending colloidal particles with attractive interactions to form a network is a common way to impart a yield stress to a fluid. Large aspect ratio cellulose microfibers are able to a form poroelastic network at low volume fractions via aggregation and entanglement, forming a gel without significantly modifying viscosity. The gels have a small but useful yield stress and a better ability to suspend particles than non-interacting higher volume fraction glasses because the sparse fiber networks can significantly restructure at small strains. Yielding behavior can thus strongly depend on the fluid microstructure.

In our study, a new active microrheology technique is developed and applied to study deformation and yielding of aqueous cellulose fiber gels. Confocal imaging shows how gel yield stress relates to structural deformation rate because of localized network restructuring. Such response is advantageous to applications like surface coatings, nasal sprays, cosmetics, and foods. Understanding the mechanism of rate- and length-scale dependent yielding, and relating microstructure changes to bulk rheology, will enhance our ability to formulate, model, and design complex fluids with novel performance.

Extended Abstract: File Not Uploaded
See more of this Session: Colloidal Hydrodynamics: Structure and Microrheology
See more of this Group/Topical: Engineering Sciences and Fundamentals