464161 Design Alternatives and Control Performance in the Pilot Scale Production of Isoamyl Acetate Via Reactive Distillation

Monday, November 14, 2016: 1:45 PM
Union Square 5 & 6 (Hilton San Francisco Union Square)
Daniel González1, Paola Bastidas2, Gerardo Rodriguez1 and Iván D. Gil2, (1)Department of Chemical and Environmental Engineering, Universidad Nacional de Colombia, Bogota, Colombia, (2)Department of Chemical and Environmental Engineering, Universidad Nacional de Colombia, BogotÁ, Colombia

In the present work, two different Reactive Distillation (RD) designs for the pilot scale production of isoamyl acetate are studied by means of steady state simulations. In the first design near stoichiometric amounts of acetic acid and isoamyl alcohol are fed directly to the reactive and rectifying sections of the RD column. On the second design, acetic acid in excess and isoamyl alcohol are first fed to a continuously stirred tank reactor (CSTR) and its product stream is fed to the reactive section of the column. Among different optimization variables, the overhead vapor flowrate appears to be the most influencing variable in the energy requirements of the processes, and its value and composition are responsible for the two liquid phase formation in the condensate. This variable also determines the global performance of the process schemes yielding a >99% conversion and >99% isoamyl acetate mass purity of the bottoms product. Having a CSTR upstream to the RD column allows an operation with a lower overhead vapor flowrate, thus a lower energy consumption is achieved for this design.

Indirect composition control of the bottoms product in the direct feed design has been implemented by controlling the temperature of one of the reactive trays. This control strategy shows a good disturbance rejection in the dynamic behavior of the main process variables to variations in the total feed rate and reactant feed ratio.


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