461686 Synthesis and Characterization of Biochar-Based Carbon Supported Metal Nanoparticles

Monday, November 14, 2016: 5:21 PM
Union Square 3 & 4 (Hilton San Francisco Union Square)
Sai Teja Neeli, Russell school of Chemical engineering, The University of Tulsa, Tulsa, OK and Hema Ramsurn, Russell School of Chemical Engineering, University of Tulsa, Tulsa, OK

Synthesis and characterization of biochar-based carbon supported metal nanoparticles

Sai Teja Neeli and Hema Ramsurn

Russell School of Chemical Engineering, University of Tulsa, Tulsa, OK 74104

Biochar is a carbon-rich solid formed after biomass has been carbonized. It is also a residue from a number of thermochemical conversion processes whereby biomass is converted to bio-oil and/or syngas. Therefore, this material is environmental-friendly and carbon-neutral. Traditionally, biochar has been used as soil amendments for the healthy growth of plants due to its retention capability of nutrients. This investigation aims to use biochar in a different manner: as a support for metal catalysts to promote green chemistry and engineering. The biochar used in this study is obtained from hydrothermal carbonization of model compounds of biomass namely lignin, cellulose and hemicellulose. This means that high pressure and temperature water is used as a benign solvent to depolymerize the model compounds to biochar. The biochar so produced is chemically activated with 0.1 M HNO3 solution resulting in activated carbon with defined micropore size distribution, high micropore volumes and large specific surface areas. Metal precursors (like iron nitrate) are then added to the biochar and dried in a convection oven at 110 o C for one week to obtain metal (iron) impregnated biochar. The dried mixture is thermally-treated in a quartz tubular reactor at 1000 o C for one hour in a nitrogen flow of 500 ml/min. These synthesized biochar based metal catalysts will then be characterized using a number of techniques including scanning electron microscope (SEM), x-ray powder diffraction (XRD), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and Brunauer-Emmett-Teller (BET) surface area analyzer. Other metal catalysts such as platinum, gold and nickel can also be impregnated on the biochar in the same manner. It is expected to observe distinct XRD patterns corresponding to graphite for the thermally treated metal-impregnated biochar, due to the conversion of the carbonaceous materials to graphite. SEM images will help not only in sizing the metal nanospheres (about 20 -60 nm) but also in determining how the metal is supported: half embedded or completely enclosed in the porous char matrix. Based on the characterization results, these metal-impregnated biochar catalyst could be tested for a number of reactions. These supports can withstand high temperatures and can even be used for gasification reactions and upgrading bio-oil during hydrogenation reactions. There is also the possibility of using bifunctional metal/acid catalysts on the biochar nanoparticles for dehydration and hydrogenation reactions and for aqueous phase processing to produce selectively targeted alkanes from glucose. The ultimate goal is to use these green catalysts to upgrade the oxygenated biofuels by removing the oxygen through various mechanisms and hence increasing the quality and heating value of the desired product. 

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See more of this Session: Sustainable and Green Product Design 
See more of this Group/Topical: Process Development Division