438522 Carbon Materials As High-Efficiency and Metal-Free Catalyst for the Synthesis of Cyclic Carbonates from CO2 and Epoxides

Sunday, November 8, 2015
Exhibit Hall 1 (Salt Palace Convention Center)
Shuangfeng Yin, Hunan University, Changsha, China

Carbon materials as high-efficiency and metal-free catalyst for the synthesis of cyclic carbonates from CO2 and epoxides

 

Dong-Hui Lan1, Lang Chen1, Chak-Tong Au1,2, Shuang-Feng Yin1 *

1 State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082,

Hunan, China

2 Department of Chemistry, Hong Kong Baptist University, Kowloon Tong,

Hong Kong

E-mail: sf_yin@hnu.edu.cn

From the viewpoints of “green chemistry” and “atom economy”, it is attractive to utilize CO2 to replace harmful reactants such as CO and phosgene for the generation of cyclic carbonates. Ionic liquids (ILs) as metal-free catalysts for the cycloaddition of CO2 to epoxides are mostly poor in activity. For good performance, the use of ILs is commonly accompanied with a co-catalyst [1].

Recently we combined Bu4NBr with graphene oxide (GO) and found that the binary system is highly efficient towards the cycloaddition of CO2 to propylene oxide (PO) at room temperature and atmospheric pressure [2]. The synergetic action between a Lewis acid and nucleophilic anion results in enhanced catalytic activity. With the realization of the effects of basic sites on CO2 adsorption and activation, we designed a Bu4NBr/Acid-Base bi-functionalized C3N4 system to catalyze the cycloaddition reaction. The catalytic activity can be improved by increasing the number of acid sites on C3N4 through the control of phosphorus amount.

Since the recycle of Bu4NBr is complex, it is desirable to immobilize the quaternary ammonium salt on a carbon material. By silylanization of GO with chlorine-terminal silanes followed by subsequent nucleophilic substitution reaction with N,N'-dimethylethylenediamine in a one-pot approach, we prepared GO functionalized with silanol group, amine and quaternary ammonium salts [3]. The non-toxic, metal-free, water-tolerant, and high-efficiency catalyst shows a TOF of 46.4 h-1 under mild condition, which is the highest among the reported CN-based heterogeneous catalysts [4]. The excellent performance is attributed to the synergetic effect of silanol group and halide anion for epoxide ring opening as well as the ability of amine for the adsorption and activation of CO2. The catalyst can be easily separated and reused for at least five times without significant loss of activity.

[1] W.Y. Gao, Y. Chen, S.Q. Ma, et al. Angew. Chem. Int. Ed., 2014, 53, 2615-2619.

[2] D.H. Lan, C.T. Au, S.F. Yin, et al. Carbon, 2014, 73, 351-360.

[3] D.H. Lan, L. Chen, S.F. Yin, et al. Carbon, 2015, 93, 22-31.

[4] J. Xu, F. Wu, Y.X. Li, et al. Catal. Sci. Technol., 2015, 5, 447-454.


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