435407 Tuning Al Spatial Distribution in ZSM-5 Membranes: A New Strategy to Improve Separation Performance and Stability of Zeolite Membranes for Dehydration of Acetic Acid

Sunday, November 8, 2015
Exhibit Hall 1 (Salt Palace Convention Center)
Liangqing Li1, Zan Chen1, Jianhua Yang2,3, Jinqu Wang1, Jinming Lu1, Yan Zhang1 and Hongcheng Guo2, (1)Chemical Engineering, Dalian University of Technology, Dalian, China, (2)Dalian University of Technology, Dalian, China, (3)Chemical Engineering of Material Science, University of Minnesota, Minneapolis, MN

Tuning Al spatial distribution in ZSM-5 membranes: a new strategy to improve separation performance and stability of zeolite membranes for dehydration of acetic acid

Liangqing Li a, Zan Chena, Jianhua Yang a,b*, Wanze Li a, Jinqu Wang a, Jinming Lu a ,Yan Zhanga, Hongchen Guoa

a:State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning,

116024, China.

 b: Department of Chemical Engineering and Materials Science, University of Minnesota, MN 55455;   

 *corresponding authors: Prof. Jianhua Yang, E-mail add.: yjianhua@dlut.edu.cn;


Dehydration of acetic acid (AcOH) by the conventional distillation is particularly energy-intensive process. Membrane pervaporation is attracting great interest for this purpose because of the greatly reduced energy requirement. However, the dehydration of AcOH is very challenging because of the demanded high acid resistance and the membrane materials are very limited.  So far the water flux, selectivity and acid resistance of the both of polymer and zeolite membranes for the dehydration of AcOH are low.

   The fabrication of a high performance zeolite membrane significantly relies on the control of essential membrane microstructures including the membrane thickness1, preferential grain orientation2 and grain boundary defects3. In the present work, a new strategy through tuning the Al spatial distribution of ZSM-5 membrane was proposed to improve the acid resistance of zeolite membrane. The organic template-free synthesis route was designed to tune the spatial distribution of ZSM-5 membrane. A novel ZSM-5 membrane with a low Si/Al ratio and homogeneous aluminum spatial distribution was achieved from the designed synthesis route and the obtained ZSM-5 membrane high selectivity and flux and improved stability for dehydration of acetic acid in a wide AcOH content range. The work firstly demonstrates that the Al spatial distribution is a key factor for tuning the separation performance of the zeolite membranes4.


      Fig. 1 Schematic illustration of preparation of the ZSM-5 membrane preparation with uniform spatial distribution


1. (a) P. Lee, X. Zhang, J. A. Stoeger, A. Malek, W. Fan, S. Kumar, W. C. Yoo, S. A. Hashimi, R. L. Penn, A. Stein and M. Tsapatsis, J. Am. Chem. Soc. 2011; 133: 493; (b) J.Hedlund, F. Jareman, A. Bons and M. Anthonis, J. Membr. Sci. 2003; 222:163.

2. Z. Lai, B. Griselda, D. Isabel, J. Nery, K. Sujaoti, M. Amat, E. Kokkoli, O. Terasaki, R. W. Thompson, M. Tsapatsis and D. G. Vlachos, Science, 2003; 300:457.

3. J. Choi, H. Jeong, M. A. Snyder, J. A. Stoeger, R. I. Masel and M. Tsapatsis, Science, 2009; 31:590.

4. Jianhua Yang, Liangqing Li, Wanze Li, Jinqu Wang,a Zan Chen, Dehong Yin, Jinming Lu, Yan Zhanga and Hongchen Guo, ChemCommu. 2014; 50:14657

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