431795 Dynamics and Rheology of Nonpolar Bigels

Thursday, November 12, 2015: 12:30 PM
Canyon B (Hilton Salt Lake City Center)
Chris Macosko1, Xiang Cheng1, LIan Bai1 and John Fruehwirth2, (1)Dept of Chemical Eng and Materials Sci, University of Minnesota, Minneapolis, MN, (2)Dept of Chemical Eng and Materials Sci., University of Minnesota, Minneapolis, MN

Bicontinuous, interfacially jammed, emulsion gels (bijels) are a novel class of materials composed of two immiscible phases with interpenetrating domains that are stabilized by a monolayer of colloidal particles at the interface. However, existing bijel systems so far all consist of at least one polar fluid, which is believed to be essential to induce electrostatic repulsion for stabilizing interfacial particles. It is not known whether two nonpolar fluids can form a bijel. Here, we experimentally achieve a bijel using styrene trimers and low molecular weight polybutene—two nonpolar fluids that are similar to polymer blends, which have technical applications. By combining laser scanning confocal microscopy, cryo-SEM and rheology measurement, we systematically investigate the dynamics and rheology of this nonpolar bijel. In contrast to previous studies on polar bijels, we observe the formation of particle patches on the interface which assemble during coarsening.  We also provide the first quantitative relation between the morphology of a bijel, the interfacial particle coverage and the shear modulus during bijel coarsening. Moreover, we reveal a previously unnoticed increase in the elastic modulus of bijels that can be attributed to the rearrangement of interfacial particles at long time scales. In addition, we also found a hydrophobic particle framework that survives after the direct remixing of the nonpolar bijel. Our study provides important insights into the formation of bijels and is the first step to explore the missing link between polar bijels and particle-stabilized polymer bicontinuous blends.

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See more of this Session: Colloidal Dispersions II
See more of this Group/Topical: Engineering Sciences and Fundamentals