421986 Selective Extraction of Rare Earth Elements from Scrap Magnets Via Membrane Solvent Extraction

Thursday, November 12, 2015: 4:30 PM
155E (Salt Palace Convention Center)
Daejin Kim1, Lawrence E. Powell1, LŠtitia H. Delmau1, Eric S. Peterson2, Jim Herchenroeder3 and Ramesh Bhave1, (1)Oak Ridge National Laboratory, Oak Ridge, TN, (2)Center for Advanced Energy Studies, Idaho National Laboratory, Idaho Falls, ID, (3)Molycorp Magnequench, Greenwood Village, CO

The use of rare earth elements (REEs) is widely prevalent in various energy applications such as rechargeable batteries, wind turbines, photovoltaic thin films, and fluorescent lighting. It is critical to ensure sufficient supply of the REEs to meet the fast growing demand in many high-tech industries. One of the approaches to increase the REE supply is to recover REEs from end-of-life products containing REEs. In view of this, a membrane solvent extraction (MSX) system utilizing hollow fiber membrane modules was developed to selectively extract REEs from neodymium-based scrap magnets from several leading industrial manufacturers. Two extractants, TODGA (tetraoctyl digylcol amide) and Cyanex 923 (trialkyl phosphine oxides), were evaluated to determine the distribution coefficient and selectivity for Nd (neodymium) and Dy (dysprosium). The effects of several experimental variables on REE extraction in the MSX system such as REE concentration, membrane configuration, and molar concentration of acid were investigated. The results of selective extraction of Nd, Dy, and Pr (Praseodymium) without co-extraction of non-REEs from NdFeB scrap magnets will be discussed along with characterization of the recovered REEs with X-ray diffraction, energy-dispersive X-ray spectroscopy, and inductively coupled plasma-optical emission spectroscopy.

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See more of this Session: Developments in Extractive Separations: Processes
See more of this Group/Topical: Separations Division