281901 On the Surface Shear Viscosity of Soluble Surfactants

Wednesday, October 31, 2012: 12:45 PM
410 (Convention Center )
Zachary A. Zell1, Suraj Deshmukh2, Christopher Tucker2 and Todd M. Squires1, (1)Chemical Engineering, University of California, Santa Barbara, Santa Barbara, CA, (2)The Dow Chemical Company, Midland, MI

The stability and flow behavior of multiphase materials like foams and emulsions are closely linked to their interfacial properties, which can be greatly affected by the presence of surfactants.  One such important property is the surface shear viscosity, as it is generally thought to enhance stability via reduced film drainage. The understanding of surfactant effects on surface shear viscosity is thus crucial to the study of such materials. However, for a common anionic surfactant used to make foams, sodium dodecyl sulfate(SDS), the reported values of measured surface viscosities vary by several orders of magnitude (0.01-100μNás/m).  In this study, we use ferromagnetic microdisks deposited at the SDS solution - air surface, as active, microrheological probes of the interface. Our oscillatory shear measurements reveal that the values of surface shear viscosity are on the order of 0.01μNás/m or lower, at which point the probe becomes Boussinesq limited. We therefore question the interpretation of previous measurements, and thus of the reported values of the surface viscosity of SDS solutions.  Instead, we suggest that the non-viscometric flow (including compression and dilation) gives rise to enhanced drag forces that do not reflect shear viscosity.  Rather, we propose that the enhanced drag coefficients in the literature are likely due to Marangoni forces and not the surface shear viscosity.  Our results suggest that the generally-believed correlation between the surface shear viscosity of surfactants, and the stability of foams and emulsions made using them, is not correct, but instead reflects other physico-chemical processes.

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See more of this Session: Interfacial and Nonlinear Flows II
See more of this Group/Topical: Engineering Sciences and Fundamentals