280103 High-Throughput Evaluation of Nanoporous Adsorbents for Post-Combustion Carbon Dioxide Capture

Wednesday, October 31, 2012: 12:30 PM
404 (Convention Center )
Tae-Hyun Bae1, Kenji Sumida1, Jarad A. Mason1, Justin J. Dutton2, Ken J. Micklash2, Steven S. Kaye3 and Jeffrey R. Long1, (1)Chemistry, University of California, Berkeley, CA, (2)Wildcat Discovery Technologies Inc., (3)Wildcat Discovery Technologies Inc., San Diego, CA

There is significant interest in developing solid adsorbents that selectively adsorb a large amount of CO2 at partial pressures applicable to COcapture processes, because the significantly lower heat capacities of solids compared to aqueous amine solutions can reduce the amount of energy required for desorbing CO2. The performance of adsorbents is generally evaluated by gas adsorption isotherms, which are phase-equilibrium analyses at many different partial pressures. Acquiring adsorption isotherms for multiple samples at many different conditions can be a tedious step that limits the rapid screening of materials. Here we report the development and use of a 28-channel high-throughput adsorption analyzer that greatly accelerates this screening process.

 Initially, we evaluated a series of zeolite adsorbents for application in post-combustion CO2 capture. Based on the CO2 and N2 adsorption isotherms obtained, the performance of zeolites at dry flue gas composition and temperature, such as CO2 uptake and CO2/N2 selectivity, was estimated. Then the performance of materials in a fixed-bed adsorber was predicted through breakthourgh simulations. Adsorption kinetics, an important consideration in designing a fixed-bed adsorber, were also investigated. The high-throughput evaluation methodology developed in this work can be applied in the discovery of robust metal-organic frameworks, a new class of nanoporous adsorbents, for the efficient capture of CO2 from flue gas.

Extended Abstract: File Not Uploaded
See more of this Session: Adsorbent Materials for Sustainable Energy
See more of this Group/Topical: Separations Division