Removal of Sulfur Compounds In Methane by Nano-Sized Magnesium Oxide

Wednesday, October 19, 2011
Exhibit Hall B (Minneapolis Convention Center)
Yo-Han Kim, Chemical and Biomolecular Engineering, Yonsei University, Seoul, South Korea

Removal of Sulfur Compounds in Methane by Nano-sized Magnesium Oxide

Yo-Han Kim, Anton Koriakin Chang-Ha Lee*

Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul, Korea

*E-mail: leech@yonsei.ac.kr, Tel: +82-2-2123-2762

Recently, nano-technologies have been adapted in the research to eliminate of toxic chemical and biological agonist. Particularly, metal oxide particles are considered as reactive adsorbents for the decontamination of toxic materials. The important feature is to enhance the surface chemical reactivity toward incoming adsorbates. It is expected that the adsorption efficiency of nano-sized MgO greater than commercially common used MgO. In general, there are three kinds of synthesis method for nano-sized MgO: Polyol, Hydrothermal, and Aerogel method.

In this study, nano-sized MgOs were synthesized with three different methods. The synthesized MgOs were characterized by XRD, BET, TGA, and TEM. The adsorptive properties and removal efficiencies of toxic compound (sulfur compounds in CH4) on MgO were tested by the breakthrough experiments. And the variation of adsorption capacity by calcination condition was investigated.

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Fig. 1. (a) TEM image of MgO and (b) XRD patterns of MgO and Mg(OH)2

Reference

[1] S. Utamapanya, K.J. Klabunde, and J.R. Schlup, "Nanoscale metal oxide particles/clusters as chemical reagents. Synthesis and properties of ultrahigh surface area magnesium hydroxide and magnesium oxide," Chem. Mater., 3 (1991), 175-181,

[2] S.H. Lim, E.J. Woo, H.J. Lee, C.H. Lee, "Synthesis of magnetite–mesoporous silica composites as adsorbents for desulfurization from natural gas," Applied Catalysis B: Environmental, 85 (2008) 71–76.


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