Renewable Energy Storage by CO2 Recycling Using High Temperature Electrolysis

Thursday, November 11, 2010: 12:55 PM
Alta Room (Marriott Downtown)
Joseph J. Hartvigsen1, Lyman Frost2, S. Elangovan2, Carl M. Stoots3, James E. O'Brien3 and Stephen Herring4, (1)Ceramatec, Inc., Salt Lake City, UT, (2)Ceramatec, Inc, Salt Lake City, UT, (3)Thermal Fluids and Heat Transfer Department, Idaho National Laboratory, Idaho Falls, ID, (4)Nuclear Science & Engineering, Idaho National Laboratory, Idaho Falls, ID

We have significantly greater renewable energy resources than can effectively be utilized by the electric grid due to intermittency and remoteness of the resources from large load centers. A further barrier to greater exploitation of renewable energy is that in some locales it may be competing with very low cost generation resources. For example, in many regions off-peak nuclear power is available at very low cost. Of much more urgent concern than electricity generation is the cost and assured availability of transportation fuels. Developing a means of storing intermittent renewable energy and off-peak nuclear energy as liquid transportation fuels offers improved economic prospects and a solution to the energy security of our transportation fuels while simultaneously reducing net CO2 emissions.

Many countries are now considering taxing CO2 emissions, which will increase the cost of products that are associated with those emissions. The most common method currently considered for dealing with CO2 emissions is the capture of the gas, pressurization, and then sequestration in either rock formations or saline aquifers. This is relatively costly in both capital investment and operation of the equipment. Also, there is the possibility that this CO2 will escape at some point in the future subjecting the CO2 generators to a perpetual and unquantifiable liability.

Ceramatec and INL have been investigating an alternative approach that converts CO2 into valuable transportation fuel. Using the solid oxide fuel cell materials set in conjunction with a non-fossil electric energy sources it is possible to generate synthesis gas (CO and H2) and oxygen from CO2 and H2O. This high temperature co-electrolysis (HTCE) process can use both thermal and electric energy inputs to electrolyze the CO2 and H2O at 100% thermodynamic efficiency. This is possible because the high temperature co-electrolysis reactions are endothermic, and the heat generated by resistance in the electrochemical device is chemically recuperated in the process. We have demonstrated conversion of this CO2 derived syngas to liquid fuels via the Fischer Tropsch process.


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See more of this Session: Developments in Electrolytic Routes to Hydrogen I
See more of this Group/Topical: Topical 8: Hydrogen Production and Storage