Morphology and Properties of Polypropylene Nanocomposites Based on a Silanized Organoclay

Thursday, November 11, 2010: 3:40 PM
Grand Ballroom G (Salt Palace Convention Center)
Matthew W. Spencer, Chemical Engineering, University of Texas, Austin, TX, D. L. Hunter, Southern Clay Products, Gonzales, TX and D. R. Paul, Department of Chemical Engineering and Texas Materials Institute, The University of Texas at Austin, Austin, TX

Non-silanized (C15A) and silanized (s-C15A) M2(HT)2 organoclays were used to form PP and PP/PP-g-MA (mass of PP-g-MA to mass of organoclay ratio of 1) nanocomposites by melt blending. The morphology and properties of the nanocomposites were evaluated using stress-strain analysis, wide-angle X-ray scattering (WAXS), transmission electron microscopy (TEM) coupled with particle analysis, and thermal mechanical analysis (TMA). The silanized organoclay increases relative modulus more than the non-silanized precursor, but not as much as either organoclay with PP-g-MA compatibilizer.

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