One solution is to increase surface area through the use of 3D Ordered Porous (3DOP) nanostructured La0.8Sr0.2Cr0.5Mn0.5O3-delta (LSCM). LSCM is a promising SOFC anode electrocatalyst. The 3DOP structure is fabricated by infiltration of LSCM precursor into a self-assembled colloidal crystal of polymer nanospheres. Sintering at high temperature results in a high surface area, ordered, inverse opal ‘honeycomb' structure. This ordered nanostructure will reduce path lengths for oxygen ion transport, provide significant surface area for the fuel oxidation reaction and enable facile gas transport in the anode. Ultimately, these factors will combine to enable reduction of direct hydrocarbon SOFC operating temperatures.