Tuesday, November 6, 2007 - 3:55 PM
296b

Optimization of Hydrogen Liquefaction Networks

Benjamin J. Davis, UCLA Chemical Engineering Department, 5531 Boelter Hall, Los Angeles, CA 90095 and Vasilios I. Manousiouthakis, Chemical Engineering Department, UCLA,, 5531 Boelter Hall, Los Angeles, CA 90095-1592.

In this work we present a method for optimizing cryogenic liquefaction networks to minimize operating cost using the Infinite DimEnsionAl State-space (IDEAS) approach. IDEAS can be used to synthesize globally optimal cryogenic liquefaction networks which include splitters, mixers, compressors, turbines, valves, flash units, and heat exchangers. No a priori network structure is presumed; the organization and interconnection of the unit operations involved is determined and optimized by the formulation itself. A similar approach was employed by Martin et al. [Globally optimal power cycle synthesis via the Infinite DimEnsionAl State-space (IDEAS) approach featuring minimum area with fixed utility; Chemical Engineering Science (58) p. 4291 – 4305, 2003] in the optimization of power cycle networks wherein heat exchange area was minimized for a fixed utility cost; here, the overall goal is to find the network which minimizes operating (energy, hot utility, cold utility, etc.) cost while obeying a given upper bound on total capital cost (heat exchange area, etc.).

The global optimality of the cryogenic liquefaction network is guaranteed, since IDEAS gives rise to infinite-dimensional convex (linear) programs whose finite-dimensional approximations are guaranteed to converge to the optimum value of the infinite problem. We will apply this approach to a hydrogen liquefaction system and compare the results with the thermodynamically ideal case and with the current state of the art in hydrogen liquefaction systems.