Monday, 31 October 2005: 8:00 AM-10:30 AM
260 (Cincinnati Convention Center)

Catalysis and Reaction Engineering Division (20)

#38 - Reactions in Near Critical and Supercritical Fluids I (20021)
Papers that address new experimental and theoretical investigations of reactions (or reactive processing) in supercritical fluid (SCF) media or gas-expanded liquids in the vicinity of their critical points are solicited. Some areas of interest are homogeneous catalytic reactions with SCF soluble ligands, heterogeneous catalysis, biphasic systems involving supercritical fluids, innovative reaction/separation schemes which take advantage of the variable solvent power of SCFs, and applications of expanded solvents.
CoChair:Keith W. Hutchenson
Chair:Bala Subramaniam
8:00 AMHydrogenation of Unsaturated Carbonyls in Scco2 as Reaction Medium over Ni-Supported Catalysts
Endalkachew Sahle-Demessie, Sridara Chandra Sehker
8:21 AMCatalytic Hydroformylation of Higher Olefins in CO2-Expanded Media: Kinetic, Mechanistic and Economic Aspects
Hong Jin, Anindya Ghosh, Jing Fang, Jon Tunge, Bala Subramaniam
8:42 AMMixing Effects on Homogeneous Catalytic Hydroformylation of 1-Octene in Co2 - Expanded Solvent
Debangshu Guha, M. P. Dudukovic, P. A. Ramachandran, Bala Subramaniam
9:03 AMPolyethylene Glycol: a Benign Solvent for Fine Chemical Synthesis
Elizabeth M. Giambra, Jason P. Hallett, Jie Lu, Jackson Ford, Charles L. Liotta, Charles A. Eckert
9:24 AMHeterogeneous Catalysis of Methyl Acetate Formation in Compressed Carbon Dioxide
Stephan Schwinghammer, Matthäus Siebenhofer, Rolf Marr
9:45 AMZeolite-Based Friedel-Crafts Acylation of Anisole in Supercritical Carbon Dioxide: Kinetics and Mechanisms
Yusuf G. Adewuyi
10:06 AMTheoretical Study of the Decomposition Mechanism of a Free Radical Initiator and Solvent Effects on the Reaction
Zhihui Gu, Yixuan Wang, Perla B. Balbuena
Sponsor:Catalysis and Reaction Engineering Division
Cosponsors:Engineering Sciences and Fundamentals; Environmental Division

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