Direct Methane to Methanol Conversion
Jonas Oxgaard1, Yongchun Tang2, Zhitao Xu1, William A. Goddard III1, Zaiwei Li3, Jihong Cheng3 and Weiqun Chen3, (1)Materials and Process Simulation Center (MSC), California Institute of Technology, Beckman Institute (139-74), Pasadena, CA 91125, (2)PEER Center, California Institute of Technology, 738 Arrow Grand Cr, Covina, CA 91722, (3)California Institute of Technology, 738 Arrow Grand Cr, Covina, CA 91722

Developing a low temperature, cost-effective, and ‘green' method for the conversion of methane via partial oxidation to methanol will have significant impact in capturing natural gas resources, in particular from stranded natural gas reserves. In the past two years, our research effort has been focused on the fundamental understanding of low temperature methane activation mediated by eco-friendly ionic liquids under oxidizing acid condition. Strong integration of theory and experimental studies gives us a new perspective on the detailed mechanistic reaction in these catalytic processes. Here we will present the role of ionic liquids in the methane activation process, the stability of ionic liquid, and how to use ionic liquids for water deactivation problems.

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Gas Conversion and Separations

The Preliminary Program for 2007 Spring National Meeting