Monday, 24 April 2006
70av

Adhesion Strength of Freshly Deposited and Annealed Nanoparticles Layers

Antonio Tricoli, Particle Technology Laboratory, ETH Zürich, Sonneggstrasse 3, ML2 F13, Zürich, 8092, Switzerland and Sotiris E. Pratsinis, PTL, ETH Zürich, Sonneggstrasse 3, ML2 F13, Zürich, 8092, Switzerland.

The adhesion strength of flame-made SnO2 nanoparticles on glass substrates was measured by gas impingement. These particles were produced by FSP (Flame spray synthesis) and directly deposited during 180 s by thermophoresis on a cooled glass substrate held over the flame. These particle-laden substrates were annealed to 200 – 600 C for 4 hours to produce different particle-substrate bonding states. All such substrates underwent gas impingement tests by a high pressure (1.8 bar) nitrogen jet (14 l/min) in a stagnation flow configuration. Adhesion strength increased with annealing temperature, with adhesion strength increase from 36 to 44 Pa from 25° C to 600° C. The apparent increase in strength is attributed to increase cohesion between the particles and the substrate by sintering and bridging.

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