Noncontinuum Effects in Nanoparticle Dynamics in Polymers
Venkat Ganesan1, Bharadwaj Narayanan2, Victor Pryamitsyn2 and Megha Surve2, (1)Department of Chemical Engineering, The University of Texas at Austin, 1 University Station, Code C0400, Austin, TX 78712, (2)The University of Texas at Austin, 1 University Station, Code C0400, Austin, TX 78712

We propose a continuum model for the dynamics of particles in polymer matrices which encompasses arbitrary size ratios of the polymer and particle. We present analytical and computer simulation results for the mobility of the particles and the viscosity of the suspension for the case of unentangled polymer melts. Our results indicate strong dependencies of the particle mobility upon the polymer-particle size ratios and much reduced intrinsic viscosities for the suspensions. These predictions rationalize some recent experimental observations on the dynamics of nanoparticles in polymer melts.

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Colloidal Hydrodynamics

The Preliminary Program for 2006 Annual Meeting