Wednesday, 2 November 2005 - 1:42 PM
347e
Use of Composite Activated Alumina Adsorbents for Separation of Hydrocarbons from Olefin Containing Streams
F. Handan Tezel1, Timothy C. Golden
2, Jon Mogan
3, and Bruno Morin
3. (1) Department of Chemical Engineering, University of Ottawa, 161 Louis-Pasteur, Ottawa, ON K1N 6N5, Canada, (2) Air Products and Chemicals, Inc., 7201 Hamilton Boulevard, Allentown, PA 18195-1501, (3) Alcan Chemicals, 4000 Development Drive, Brockville, ON K6V 5V5, Canada
Adsorption of ethylene, acetylene, propylene and propyne has been studied on several activated alumina based adsorbents. Henry's Law constants, heat of adsorption values as well as adsorption isotherms of these components were determined. Concentration Pulse Chromatographic technique was used for the determination of Henry's Law constants and heat of adsorption values. For the determination of adsorption isotherms, a constant volume system was used. Coking studies were also carried out to see any coke formation will happen during repeated cycles of adsorption and desorption. Adsorbents studied include plain activated alumina, its chemically modified forms, as well as its composites with zeolites.
Results show that propyne was the most strongly adsorbed component with the highest Henry's Law constant and the highest heat of adsorption values.
Web Page:
www.genie.uottawa.ca/~tezel/tezel.htm
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